SURE: Web Posters from SURE 2002

Matrix Isolation Laser Spectroscopic Investigations of Uranium Fluorides
Mariana J. Ortiz, Christopher Lue, Jonathan C. Rienstra-Kiracofe, Michael C. Heaven
Department of Chemistry, Emory University, Atlanta GA 30322

Abstract

Molecules of uranium hexafluoride (UF6) trapped in a cryogenic argon matrix were electronically excited using ultraviolet light from an Nd:YAG laser. The fluorescence produced as the molecules returned to their ground electronic state was analyzed using a monochromator to scan wavelengths between 400-450 nm. We determined the accuracy and reliability of our technique and experimental apparatus by comparing resulting excitation spectra to spectra obtained in previous studies of uranium hexafluoride. This was done by assigning the peaks in the excitation spectra we obtained to known electronic transitions of the molecule and comparing their values. Currently, we are disintegrating UF6 by passing it through a microwave discharge and the resulting molecular fragments will be characterized.